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Ammonia is an important industrial chemical with an estimated worldwide production exceeding 150 million metric tons. About 70% of ammonia is used to make nitrate fertilizers. Unfortunately, the production of ammonia is energy and it's a major source of carbon dioxide emission. Synthesis of ammonia is by the Bosch-Haber process developed in 1909. While the reaction of nitrogen and hydrogen to form ammonia is exothermic, it does not occur spontaneously. A catalyst of potassium-promoted iron allows synthesis at high temperature and high pressure, while a ruthenium catalyst allows for reaction at a lower pressure. Since the Bosch-Haber process is a process in widespread use that contributes to global warming, it's a prime candidate for improvement, but no major improvements in ammonia synthesis have appeared in the century after its discovery. A recent study in Science by physicists at the Technical University of Denmark has looked at how lanthanum atoms on a cobalt catalyst quench the...
11 months ago

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More from Tikalon Blog by Dev Gualtieri

Tikalon Blog Archive

Tikalon Blog is now in archive mode. Here's a directory of links to easily printed and saved articles. If you're willing to wait a while for the download, a zip file of all the blog articles can be found at the link below. Note, however, that these articles are copyrighted and can't be used to train artificial intelligent agents. Individuals are free to republish single articles on their personal websites.

9 months ago 31 votes
Spiderweb Microphone

Microphones convert sound into an electrical signal for subsequent amplification, as in auditorium public address systems; or transmission, as in landline and mobile phones. The most common types of microphones are carbon, used in early telephones, condenser, electret, dynamic, ribbon, crystal and MEMS. All these microphones operate as transducers that convert sound pressure into an electrical signal. This makes them also sensitive to noise caused by air molecules bouncing against their diaphragms. In an effort to solve this thermal noise problem, a team of mechanical engineers has investigated a sound sensing approach that uses viscous air flow rather than sound pressure. Viscous flow is what vibrates spiderwebs in gentle breezes. Air flow passing a thread of a spiderweb drags the thread. They demonstrated sound detection by a simulated spiderweb, an array of thin cantilever beams. The beams were 0.5 micrometer thick silicon nitride placed over a hole in a silicon wafer, and a laser was used to measure the displacement of the microbeams, first in response to thermal noise, and then in response to sound waves from 100 to 1000 Hz. The cantilever velocity matched that of the sound wave, irrespective of the length or width of the beam. The demonstrated cantilever microphone is about 50 dBa less sensitive than the best pressure-based microphones; but, pressure microphones have been perfected over a span of 150 years. As the lead author of the paper comments, "Detecting air flow as a way to sense sound has largely been ignored by researchers, but the principles show that it's worth considering."

9 months ago 32 votes
Adornment

"Form follows function" is a maxim that an object's shape and appearance should be defined only by its purpose or function. A quick perusal of any antique shop will show that this maxim is generally ignored. Humans (Homo sapiens) have been called "naked apes," but we and our close species cousins quickly adopted the concept of wearing the fur skins of animals for protection. Our ancestors were likely much more interested in how they would obtain their next meal than how stylish they appeared in hyena fur. As human culture progressed, people desired to distinguish themselves from others; and, what could be an easier way to do that than through dress. This is accomplished by the simple technique of dyeing drab natural fibers, but the simple sewing needle is a technical innovation that's lead to a means of producing more ornate dress. A recent open access article in Science Advances investigates the use of delicate eyed needles in the Paleolithic as the means for producing refined, ornamented dress. One argument for clothing's becoming a means of decoration is that traditional body decoration, such as body painting with ochre, weren't effective in cold climates, since clothing was needed all the time for survival. Homo sapiens arrived in Europe at around 45,000 BC, and the earliest known eyed needles appeared in Siberia around 40,000 BC, in the Caucasus around 38,000 BC, in West Asia around 30,000 BC, and in Europe around 26,000 BC. Clothing the human body regardless of climate is a social practice that's persisted to this day. The eyed needle combined the processes of hole puncture and threading to allow finer and more efficient sewing.

9 months ago 29 votes
Brain Size

Deep thought is what distinguishes humans from other animals. The brain is the medium for thought; so, there's the idea that brain size is important, with larger brains allowing more profound thought. Larger brains in hominids appears to have an evolutionary advantage, but the largest animals do not have proportionally larger brains. For the last century, conventional wisdom was that body mass in mammals could be described by a power law. A British research team has created a large dataset of brain and body sizes from about 1,500 species to determine the trend in brain size evolution, finding that the trend is brain size and body mass is not log-linear, but rather log-curvilinear, plateauing at high body mass. The research team found that all groups of mammals demonstrated rapid bursts of evolutionary change, not only towards larger brain size, but smaller as well. Bats very rapidly reduced their brain size, suggesting that flight may have imposed an evolutionary constraint. Homo sapiens has evolved more than twenty times faster than all other mammalian species, resulting in the massive brain size of modern man. Primates, rodents, and carnivores show a tendency for increase in relative brain size as they evolved. It appears that there is something preventing brains from getting too big, perhaps because big brains beyond a certain size are simply too costly to maintain. This upper limit of brain size applies to animals with very different biology.

9 months ago 23 votes
Ice Formation

In today's bigger is better world, you don't order a large coffee, you order a 20 fluid ounce Venti coffee. From 1987 through 2004, McDonald's restaurants had a supersize option for larger than large portions of its French fries and soft drinks. The prefix, super, has been used to describe supercooling, the unexpected cooling without a phase change when liquids can be cooled below their freezing points without solidifying. Water has many unusual properties, and these are most probably the result of water molecule being small, and the force holding these molecules together in a liquid or solid arising from hydrogen bonding. Supercooled water is a hazard to aviation, since supercooled water droplets often existing in cumulus and stratus clouds will instantly freeze on aircraft surfaces and plug the Pitot tubes that indicate airspeed. It's easy to create supercooled water in the laboratory. You just need to purify the water to remove contained minerals. The mineral crystals act as nucleation sites. Bacteria and fungi are efficient natural ice nucleators because of the way their proteins act as ice templates. The best such natural ice nucleators the Pseudomonas syringae bacterium, which is used to make artificial snow. Larger protein molecules are usually better at ice nucleation, but small fungal proteins are good at ice nucleation when they clump into larger aggregates. Scientists at the University of Utah have developed a model for prediction of the nucleation temperature of ice on a given surface. Model parameters include the shapes of surface defects, and appropriately sized and shaped surface bumps and depressions can squeeze water molecules into configurations that make it easier or harder for ice to form.

10 months ago 19 votes

More in science

How to redraw a city

The planning trick that created Japan's famous urbanism

7 hours ago 2 votes
Wet Labs Shouldn’t Be Boring (for young scientists) | Out-Of-Pocket

This is the first touchpoint for science, we should make it more enticing

10 hours ago 2 votes
How AI Models Are Helping to Understand — and Control — the Brain

Martin Schrimpf is crafting bespoke AI models that can induce control over high-level brain activity. The post How AI Models Are Helping to Understand — and Control — the Brain first appeared on Quanta Magazine

an hour ago 1 votes
Discarded U.K. Clothing Dumped in Protected Wetlands in Ghana

Heaps of discarded clothing from the U.K. have been dumped in protected wetlands in Ghana, an investigation found. Read more on E360 →

3 hours ago 1 votes
How Sewage Recycling Works

[Note that this article is a transcript of the video embedded above.] Wichita Falls, Texas, went through the worst drought in its history in 2011 and 2012. For two years in a row, the area saw its average annual rainfall roughly cut in half, decimating the levels in the three reservoirs used for the city’s water supply. Looking ahead, the city realized that if the hot, dry weather continued, they would be completely out of water by 2015. Three years sounds like a long runway, but when it comes to major public infrastructure projects, it might as well be overnight. Between permitting, funding, design, and construction, three years barely gets you to the starting line. So the city started looking for other options. And they realized there was one source of water nearby that was just being wasted - millions of gallons per day just being flushed down the Wichita River. I’m sure you can guess where I’m going with this. It was the effluent from their sewage treatment plant. The city asked the state regulators if they could try something that had never been done before at such a scale: take the discharge pipe from the wastewater treatment plant and run it directly into the purification plant that produces most of the city’s drinking water. And the state said no. So they did some more research and testing and asked again. By then, the situation had become an emergency. This time, the state said yes. And what happened next would completely change the way cities think about water. I’m Grady and this is Practical Engineering. You know what they say, wastewater happens. It wasn’t that long ago that raw sewage was simply routed into rivers, streams, or the ocean to be carried away. Thankfully, environmental regulations put a stop to that, or at least significantly curbed the amount of wastewater being set loose without treatment. Wastewater plants across the world do a pretty good job of removing pollutants these days. In fact, I have a series of videos that go through some of the major processes if you want to dive deeper after this. In most places, the permits that allow these plants to discharge set strict limits on contaminants like organics, suspended solids, nutrients, and bacteria. And in most cases, they’re individualized. The permit limits are based on where the effluent will go, how that water body is used, and how well it can tolerate added nutrients or pollutants. And here’s where you start to see the issue with reusing that water: “clean enough” is a sliding scale. Depending on how water is going to be used or what or who it’s going to interact with, our standards for cleanliness vary. If you have a dog, you probably know this. They should drink clean water, but a few sips of a mud puddle in a dirty street, and they’re usually just fine. For you, that might be a trip to the hospital. Natural systems can tolerate a pretty wide range of water quality, but when it comes to drinking water for humans, it should be VERY clean. So the easiest way to recycle treated wastewater is to use it in ways that don’t involve people. That idea’s been around for a while. A lot of wastewater treatment plants apply effluent to land as a disposal method, avoiding the need for discharge to a natural water body. Water soaks into the ground, kind of like a giant septic system. But that comes with some challenges. It only works if you’ve got a lot of land with no public access, and a way to keep the spray from drifting into neighboring properties. Easy at a small scale, but for larger plants, it just isn’t practical engineering. Plus, the only benefits a utility gets from the effluent are some groundwater recharge and maybe a few hay harvests per season. So, why not send the effluent to someone else who can actually put it to beneficial use? If only it were that simple. As soon as a utility starts supplying water to someone else, things get complicated because you lose a lot of control over how the effluent is used. Once it's out of your hands, so to speak, it’s a lot harder to make sure it doesn’t end up somewhere it shouldn’t, like someone’s mouth. So, naturally, the permitting requirements become stricter. Treatment processes get more complicated and expensive. You need regular monitoring, sampling, and laboratory testing. In many places in the world, reclaimed water runs in purple pipes so that someone doesn’t inadvertently connect to the lines thinking they’re potable water. In many cases, you need an agreement in place with the end user, making sure they’re putting up signs, fences, and other means of keeping people from drinking the water. And then you need to plan for emergencies - what to do if a pipe breaks, if the effluent quality falls below the standards, or if a cross-connection is made accidentally. It’s a lot of work - time, effort, and cost - to do it safely and follow the rules. And those costs have to be weighed against the savings that reusing water creates. In places that get a lot of rain or snow, it’s usually not worth it. But in many US states, particularly those in the southwest, this is a major strategy to reduce the demand on fresh water supplies. Think about all the things we use water for where its cleanliness isn’t that important. Irrigation is a big one - crops, pastures, parks, highway landscaping, cemeteries - but that’s not all. Power plants use huge amounts of water for cooling. Street sweeping, dust control. In nearly the entire developed world, we use drinking-quality water to flush toilets! You can see where there might be cases where it makes good sense to reclaim wastewater, and despite all the extra challenges, its use is fairly widespread. One of the first plants was built in 1926 at Grand Canyon Village which supplied reclaimed water to a power plant and for use in steam locomotives. Today, these systems can be massive, with miles and miles of purple pipes run entirely separate from the freshwater piping. I’ve talked about this a bit on the channel before. I used to live near a pair of water towers in San Antonio that were at two different heights above ground. That just didn’t make any sense until I realized they weren’t connected; one of them was for the reclaimed water system that didn’t need as much pressure in the lines. Places like Phoenix, Austin, San Antonio, Orange County, Irvine, and Tampa all have major water reclamation programs. And it’s not just a US thing. Abu Dhabi, Beijing, and Tel Aviv all have infrastructure to make beneficial use of treated municipal wastewater, just to name a few. Because of the extra treatment and requirements, many places put reclaimed water in categories based on how it gets used. The higher the risk of human contact, the tighter the pollutant limits get. For example, if a utility is just selling effluent to farmers, ranchers, or for use in construction, exposure to the public is minimal. Disinfecting the effluent with UV or chlorine may be enough to meet requirements. And often that’s something that can be added pretty simply to an existing plant. But many reclaimed water users are things like golf courses, schoolyards, sports fields, and industrial cooling towers, where people are more likely to be exposed. In those cases, you often need a sewage plant specifically designed for the purpose or at least major upgrades to include what the pros call tertiary treatment processes - ways to target pollutants we usually don’t worry about and improve the removal rates of the ones we do. These can include filters to remove suspended solids, chemicals that bind to nutrients, and stronger disinfection to more effectively kill pathogens. This creates a conundrum, though. In many cases, we treat wastewater effluent to higher standards than we normally would in order to reclaim it, but only for nonpotable uses, with strict regulations about human contact. But if it’s not being reclaimed, the quality standards are lower, and we send it downstream. If you know how rivers work, you probably see the inconsistency here. Because in many places, down the river, is the next city with its water purification plant whose intakes, in effect, reclaim that treated sewage from the people upstream. This isn’t theoretical - it’s just the reality of how humans interact with the water cycle. We’ve struggled with the problems it causes for ages. In 1906, Missouri sued Illinois in the Supreme Court when Chicago reversed their river, redirecting its water (and all the city’s sewage) toward the Mississippi River. If you live in Houston, I hate to break it to you, but a big portion of your drinking water comes from the flushes and showers in Dallas. There have been times when wastewater effluent makes up half of the flow in the Trinity River. But the question is: if they can do it, why can’t we? If our wastewater effluent is already being reused by the city downstream to purify into drinking water, why can’t we just keep the effluent for ourselves and do the same thing? And the answer again is complicated. It starts with what’s called an environmental buffer. Natural systems offer time to detect failures, dilute contaminants, and even clean the water a bit—sunlight disinfects, bacteria consume organic matter. That’s the big difference in one city, in effect, reclaiming water from another upstream. There’s nature in between. So a lot of water reclamation systems, called indirect potable reuse, do the same thing: you discharge the effluent into a river, lake, or aquifer, then pull it out again later for purification into drinking water. By then, it’s been diluted and treated somewhat by the natural systems. Direct potable reuse projects skip the buffer and pipe straight from one treatment plant to the next. There’s no margin for error provided by the environmental buffer. So, you have to engineer those same protections into the system: real-time monitoring, alarms, automatic shutdowns, and redundant treatment processes. Then there’s the issue of contaminants of emerging concern: pharmaceuticals, PFAS [P-FAS], personal care products - things that pass through people or households and end up in wastewater in tiny amounts. Individually, they’re in parts per billion or trillion. But when you close the loop and reuse water over and over, those trace compounds can accumulate. Many of these aren’t regulated because they’ve never reached concentrations high enough to cause concern, or there just isn’t enough knowledge about their effects yet. That’s slowly changing, and it presents a big challenge for reuse projects. They can be dealt with at the source by regulating consumer products, encouraging proper disposal of pharmaceuticals (instead of flushing them), and imposing pretreatment requirements for industries. It can also happen at the treatment plant with advanced technologies like reverse osmosis, activated carbon, advanced oxidation, and bio-reactors that break down micro-contaminants. Either way, it adds cost and complexity to a reuse program. But really, the biggest problem with wastewater reuse isn’t technical - it’s psychological. The so-called “yuck factor” is real. People don’t want to drink sewage. Indirect reuse projects have a big benefit here. With some nature in between, it’s not just treated wastewater; it’s a natural source of water with treated wastewater in it. It’s kind of a story we tell ourselves, but we lose the benefit of that with direct reuse: Knowing your water came from a toilet—even if it’s been purified beyond drinking water standards—makes people uneasy. You might not think about it, but turning the tap on, putting that water in a glass, and taking a drink is an enormous act of trust. Most of us don’t understand water treatment and how it happens at a city scale. So that trust that it’s safe to drink largely comes from seeing other people do it and past experience of doing it over and over and not getting sick. The issue is that, when you add one bit of knowledge to that relative void of understanding - this water came directly from sewage - it throws that trust off balance. It forces you not to rely not on past experience but on the people and processes in place, most of which you don’t understand deeply, and generally none of which you can actually see. It’s not as simple as just revulsion. It shakes up your entire belief system. And there’s no engineering fix for that. Especially for direct potable reuse, public trust is critical. So on top of the infrastructure, these programs also involve major public awareness campaigns. Utilities have to put themselves out there, gather feedback, respond to questions, be empathetic to a community’s values, and try to help people understand how we ensure water quality, no matter what the source is. But also, like I said, a lot of that trust comes from past experience. Not everyone can be an environmental engineer or licensed treatment plant operator. And let’s be honest - utilities can’t reach everyone. How many public meetings about water treatment have you ever attended? So, in many places, that trust is just going to have to be built by doing it right, doing it well, and doing it for a long time. But, someone has to be first. In the U.S., at least on the city scale, that drinking water guinea pig was Wichita Falls. They launched a massive outreach campaign, invited experts for tours, and worked to build public support. But at the end of the day, they didn’t really have a choice. The drought really was that severe. They spent nearly four years under intense water restrictions. Usage dropped to a third of normal demand, but it still wasn’t enough. So, in collaboration with state regulators, they designed an emergency direct potable reuse system. They literally helped write the rules as they went, since no one had ever done it before. After two months of testing and verification, they turned on the system in July 2014. It made national headlines. The project ran for exactly one year. Then, in 2015, a massive flood ended the drought and filled the reservoirs in just three weeks. The emergency system was always meant to be temporary. Water essentially went through three treatment plants: the wastewater plant, a reverse osmosis plant, and then the regular water purification plant. That’s a lot of treatment, which is a lot of expense, but they needed to have the failsafe and redundancy to get the state on board with the project. The pipe connecting the two plants was above ground and later repurposed for the city’s indirect potable reuse system, which is still in use today. In the end, they reclaimed nearly two billion gallons of wastewater as drinking water. And they did it with 100% compliance with the standards. But more importantly, they showed that it could be done, essentially unlocking a new branch on the skill tree of engineering that other cities can emulate and build on.

yesterday 4 votes